Ag₂O@UiO-66 new thin film as p-n heterojunction: permanent photoreduction of hexavalent Cr.

Abstract

The new nanosphere Ag₂O@UiO-66 thin-film was synthesized on a stainless steel mesh surface <i>via</i> an electrophoretic deposition method, and is used as an effective and low-cost photocatalyst using visible light. The synthesized nanocomposite was used to perform photo-reduction of Cr(vi) ions under white light irradiation. The best removal rate (72% after 15 minutes) was obtained by the film with 0.034 grams of deposited composite having relative percentages of Ag₂O : UiO-66 of 70 : 30. The interesting obtained results confirm that the p-n heterojunction of the composite is the main cause of the desired charge separation and the photoreduction speed increase. In the following, the resulting compounds were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), transmittance electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), energy diffraction X-ray spectroscopy (EDAX) and the Brunauer, Emmett, and Teller (BET) method. Scavenging studies performed in the presence of familiar scavengers confirmed that superoxide radicals (˙O₂^-) and dissolved oxygen gas have a significant role in the photocatalytic reduction process.