Development and Evaluation of a Slow-Release Occluded Fertilizer Employing Functionalized Biosolids as a Support Matrix.

Abstract

In this study, a slow-release fertilizer (SRF) was obtained by occluding NPK 10-10-10 into two matrices and compared with the uncoated mineral fertilizer (F). The first matrix, FOMI, used biosolids/paper sludge at 3:1 (<i>w</i>/<i>w</i>); the second, FOMII, used biosolids/clay at 1:1 (<i>w</i>/<i>w</i>). Materials and pellets were physiochemically and microbiologically characterized. Release kinetics were evaluated in water and in soil columns packed with acid-washed sand; matrix-only controls and sand blanks confirmed negligible background N, P, and K. The uncoated mineral fertilizer (F) showed a rapid burst, whereas occlusion slowed release. FOMII reduced release relative to F, and FOMI produced the slowest, controlled profiles: kinetic fits yielded lower k values for FOMI than for FOMII and F. FOMI also exhibited higher water-retention capacity (WRC) and cation-exchange capacity (CEC), consistent with its greater organic-matter content. In soil, FOMI released less than 15% at 48 h and no more than 75% at 30 d, meeting European Committee for Standardization (CEN) SRF criteria; FOMII released faster than FOMI but slower than F, which exceeded 90% within the test period. Therefore, FOMI is a biodegradable, low-cost SRF that improves fertilizer-use efficiency while returning organic matter to agricultural soils; FOMII shows intermediate yet beneficial performance.