Peer-reviewed veterinary case report
Evolution of LiNi<sub>0.8</sub>Mn<sub>0.1</sub>Co<sub>0.1</sub>O<sub>2</sub> (NMC811) Cathodes for Li-Ion Batteries: An <i>In Situ</i> Electron Paramagnetic Resonance Study.
- Year:
- 2025
- Authors:
- Wang B et al.
- Affiliation:
- Department of Chemistry · United Kingdom
Abstract
The rapid voltage and capacity fade of the otherwise promising Ni-rich layered LiNi<sub>0.8</sub>Mn<sub>0.1</sub>Co<sub>0.1</sub>O<sub>2</sub> (NMC811) cathode are the primary obstacles to its successful commercialization in lithium-ion batteries (LIBs). Here, <i>in situ</i> electrochemical electron paramagnetic resonance (EPR) spectroscopy is employed to gain insight into the cation redox behavior of the NMC811 cathode during the cell charge/discharge process. Different oxidation states of Ni ions are detected by variations in the signal of the EPR spectra. <i>Ex situ</i> studies of NMC811 at different SOC levels also confirm changes in the local Mn-Ni environment. A comparison of <i>in situ</i> studies on fresh and cycled NMC811 electrodes demonstrates that the fundamental redox processes remain unchanged upon cycling of the material. Finally, dissolved Mn and Co ions from the bulk are found using <i>ex situ</i> EPR characterization of the cycled cathode and separator. The dissolution of these metal ions can accelerate the degradation of the entire battery.
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Search related cases →Original publication: https://europepmc.org/article/MED/40302850