Fabrication of Copper Nanowires Highly Conductive and Flexible Circuits by Direct Ink Writing.

Abstract

Direct ink writing (DIW) has emerged as a promising method for fabricating flexible electronics. Copper nanowires are a key material for the conductive inks required for this technology. However, copper nanowires suffer from significant challenges, including low aspect ratios, poor oxidation resistance, and difficulty in printing. In this study, a liquid-phase reduction method was used to synthesize copper nanowires with a high aspect ratio (up to 2884) and excellent oxidation resistance. The conductive ink was prepared using ethylene glycol, isopropanolamine (MIPA), and ethanol as solvents. Rheological dynamics simulations were used to investigate the influence of printing parameters on ink printing accuracy, ultimately achieving precise control of the printing process. High-precision copper nanowire flexible circuits with a low resistivity of 2.11 μΩ·cm were fabricated under thermal sintering conditions using the DIW method. These circuits exhibited excellent adhesion, flexural behavior, and water resistance, demonstrating significant practical significance for the low-cost fabrication of high-precision flexible electronic devices.