Influence of Coexisting Copper and Zinc on the Adsorption and Migration of Sulfadiazine in Soda Saline-Alkali Wetland Soils: A Simulation Approach.

Abstract

This study investigates the adsorption and migration of sulfadiazine (SDZ) in soda saline-alkali soils under Cu/Zn co-pollution using equilibrium adsorption and soil column experiments. Freundlich and Langmuir isothermal models, combined with Hydrus-1D two-site modeling, revealed concentration-dependent interactions. Low Cu (10-100 mg kg^-1) and Zn (10-100 mg kg^-1) enhanced SDZ adsorption via charge regulation and complexation, while high concentrations (300 mg kg^-1) suppressed adsorption through competitive adsorption and hydroxide precipitation. Synergistic Cu-Zn coexistence further reduced adsorption to 3.035 mg kg^-1. Freundlich modeling (R² = 0.922-0.995) outperformed Langmuir, confirming adsorption site heterogeneity. Column experiments showed Cu (300 mg kg^-1) and Zn (300 mg kg^-1) accelerated SDZ migration (peaks 0.93-0.94), delaying breakthrough versus Br^-. Hydrus-1D simulations (R² ≥ 0.915, RMSE < 0.1) effectively quantified nonlinear dynamics between instantaneous adsorption sites (f = 0.101-0.554) and metal concentrations. Results demonstrate heavy metals critically regulate antibiotic fate via concentration-dependent mechanisms in saline-alkali ecosystems.