Mechanical Properties of Biochar-Sulfur Composites.

Abstract

The study examines the mechanical strength of sulfur-biochar composites (SBCs), an underexplored area with potential for developing robust materials. Sulfur production, primarily from specialized extraction and waste generation in petroleum refining, yields about 70 million tons annually, necessitating efficient waste management. SBCs were produced using waste-derived biochar and elemental sulfur at varying sulfur contents (60-80%) and employing two fabrication methods: a muffle furnace and an electric burner. The mechanical performance of the composites was evaluated through strength and displacement measurements, with particular emphasis on the influence of processing method and sulfur content. The results demonstrate that both sulfur content and fabrication method significantly affect the mechanical behavior of SBCs. An increase in sulfur content led to a systematic improvement in ultimate strength for all samples. However, composites produced using the electric burner exhibited markedly higher ultimate forces and lower displacements compared to those fabricated in the muffle furnace, indicating superior strength and reduced brittleness. The enhanced performance is attributed to improved sulfur distribution and more effective infiltration of liquid sulfur into the porous biochar structure. These findings confirm the synergistic effect of combining sulfur with biochar and highlight the critical role of processing conditions in developing mechanically robust sulfur-biochar composites suitable for sustainable material applications.