Peer-reviewed veterinary case report
Nickel Phosphine Complexes: Synthesis, Characterization, and Behavior in the Polymerization of 1,3-Butadiene.
- Year:
- 2025
- Authors:
- Guelfi M et al.
- Affiliation:
- Dipartimento di Chimica e Chimica Industriale · Italy
Abstract
Several nickel dichloride phosphine complexes have been synthesized, their crystalline structure determined, and their behavior, in combination with methylaluminoxane, in the polymerization of butadiene has been examined. High-<i>cis</i> polybutadienes were consistently obtained, regardless of the nature of the phosphine coordinated to the metal and the methylaluminoxane/Ni molar ratio used, contrary to what was previously observed in the polymerization of butadiene with analogous cobalt phosphine complexes, in which catalytic selectivity was found to be strongly influenced by these two factors. An interpretation for such different behavior is provided.
Find similar cases for your pet
PetCaseFinder finds other peer-reviewed reports of pets with the same symptoms, plus a plain-English summary of what was tried across them.
Search related cases →Original publication: https://europepmc.org/article/MED/41375250