Rational Design of Trimetallic Sulfide Electrodes for Alkaline Water Electrolysis with Ampere-Level Current Density.

Abstract

Electrochemical water splitting is considered an environmentally friendly approach to hydrogen generation. However, it is difficult to achieve high current density and stability. Herein, we design an amorphous/crystalline heterostructure electrode based on trimetallic sulfide over nickel mesh substrate (NiFeMoS/NM), which only needs low overpotentials of 352 mV, 249 mV, and 360 mV to achieve an anodic oxygen evolution reaction (OER) current density of 1 A cm^-2 in 1 M KOH, strong alkaline electrolyte (7.6 M KOH), and alkaline-simulated seawater, respectively. More importantly, it also shows superior stability with negligible decay after continuous work for 120 h at 1 A cm^-2 in the strong alkaline electrolyte. The excellent OER performance of the as-obtained electrode can be attributed to the strong electronic interactions between different metal atoms, abundant amorphous/crystalline hetero-interfaces, and 3D porous nickel mesh structure. Finally, we coupled NiFeMoS/NM as both the anode and cathode in the anion exchange membrane electrolyzer, which can achieve low cell voltage and high stability at ampere-level current density, demonstrating the great potential of practicability.