Research on Curing Reaction Kinetics and Curing Process of Nitrate Ester Plasticized Polyether (NEPE) Propellants.

Abstract

The casting-curing process is a common technology for manufacturing the Nitrate Ester Plasticized Polyether (NEPE) propellants. The curing process involves a coupled thermal-chemical reaction of the adhesive systems of propellant, which influences the curing stage. Using GID 16 software, a propellant grain curing simulation model was conducted. This study employs a model-fitting method based on non-isothermal DSC experiments to analyze the curing reaction kinetics of propellants. Two methods, Kissinger and Ozawa, were used to determine the activation energy of the curing reaction. The reaction activation energy obtained by the Ozawa method was chosen as the simulation parameter Ea = 59.378 based on the fitting coefficients. The simulation comprehensively onsidered flow, temperature, and curing reaction parameters, achieving multi-field coupling of thermal and curing degree fields during the curing process. The macroscopic temperature variations of the pillars were monitored using thermocouples. The experimental results show that the final curing temperature is stable at about 48.2 °C. At about 21,000 s, the overall temperature of the grain converges. The experimental results were compared with the simulation results, revealing minor discrepancies. Experimental and simulation methods were used to verify the changing law of the temperature field inside the propellant grain. Furthermore, these results have significance for improving the casting-curing industrial process of the composite solid propellant.