Synthesis and characterization of SSM@NiO/TiO₂ p-n junction catalyst for bisphenol a degradation.

Abstract

Photocatalyst immobilization on support materials is essential for large-scale applications. Here, we describe growth of a p-n junction catalyst (NiO/TiO₂) on a stainless-steel mesh (SSM) support using a facile hydrothermal method. The morphological superiority of the composite over previously reported NiO/TiO₂ catalysts was probed using scanning and transmission electron microscopy. Flower petal-like NiO grew uniformly on SSM, which was evenly covered by TiO₂ nanoparticles. Theoretical and experimental X-ray diffraction patterns were compared to analyze the development of the composite during various stages of synthesis. The photocatalytic activity of a powdered catalyst and SSM@catalyst was compared by measuring bisphenol A (BPA) degradation. SSM@NiO/TiO₂ achieved the highest rate of BPA degradation, removing 96% of the BPA in 120 min. Scavenging experiments were used to investigate the charge separation and degradation mechanism. SSM@NiO/TiO₂ showed excellent reusability potential, achieving and sustaining 91% BPA removal after 10 rounds of cyclic degradation. Reusability performance, composite resilience, apparent quantum yields, and figures of merit suggest that SSM@NiO/TiO₂ has excellent utility for practical applications.